Process for bonding interstitial epoxy adhesive for fabrication of printhead structures in high density printheads

ABSTRACT

A method for forming an ink jet printhead comprises processing an epoxy adhesive such that negative effects from physical contact with particular inks are reduced or eliminated. Conventional adhesives processed using conventional techniques are known to gain weight and squeeze out when exposed to certain inks such as ultraviolet inks and pigmented inks. An embodiment of the present teachings can include processing of a particular adhesive such that the resulting epoxy adhesive is suitable for printhead applications.

TECHNICAL FIELD

The present teachings relate to the field of ink jet printing devicesand, more particularly, to methods and structures for high densitypiezoelectric ink jet print heads and a printer including a high densitypiezoelectric ink jet print head.

BACKGROUND

Drop on demand ink jet technology is widely used in the printingindustry. Printers using drop on demand ink jet technology can useeither thermal ink jet technology or piezoelectric technology. Eventhough they are more expensive to manufacture than thermal ink jets,piezoelectric ink jets are generally favored, for example because theycan use a wider variety of inks.

Piezoelectric ink jet print heads include an array of piezoelectricelements (i.e., piezoelectric transducers or PZTs). One process to formthe array can include detachably bonding a blanket piezoelectric layerto a transfer carrier with an adhesive, and dicing the blanketpiezoelectric layer to form a plurality of individual piezoelectricelements. A plurality of dicing saw passes can be used to remove all thepiezoelectric material between adjacent piezoelectric elements toprovide the correct spacing between each piezoelectric element.

Piezoelectric ink jet print heads can typically further include aflexible diaphragm to which the array of piezoelectric elements isattached. When a voltage is applied to a piezoelectric element,typically through electrical connection with an electrode electricallycoupled to a power source, the piezoelectric element bends or deflects,causing the diaphragm to flex which expels a quantity of ink from achamber through a nozzle. The flexing further draws ink into the chamberfrom a main ink reservoir through an opening to replace the expelledink.

The formation of ink jet printheads typically requires lamination ofmultiple layers of materials as part of their fabrication. Traditionalprinthead designs may use layers of gold-plated stainless steel sheetmetal with features that are photochemically etched and then brazedtogether to form robust structures. However, with the continued drive toimprove cost and performance, use of alternate materials and bondingprocesses may be used. While polymer layers can be used as a replacementof some sheet metal components, polymers require adhesives with suitableproperties to bond to each other and to metal layers.

For example, the adhesive must be chemically compatible with the inksused within the printhead. Further, the adhesive should have certainphysical properties that reduce printhead failures during use. Anadhesive should have a good bond strength, a low squeeze out to preventblocking of the fluid path, and should be sufficiently resistant tooxidation with elevated temperatures during use. Also, some adhesivesmay increase in weight and swell, or become less compliant and morestiff during use when exposed to certain inks and elevated temperatures,which can result in leakage of ink or other failure modes. Some of thesefailures may occur only after extended use of the printhead.

SUMMARY

The following presents a simplified summary in order to provide a basicunderstanding of some aspects of one or more embodiments of the presentteachings. This summary is not an extensive overview, nor is it intendedto identify key or critical elements of the present teachings nor todelineate the scope of the disclosure. Rather, its primary purpose ismerely to present one or more concepts in simplified form as a preludeto the detailed description presented later.

In an embodiment, a method for forming an ink jet printhead can includeheating a first surface of a first substrate to a temperature of between40° C. and 120° C., contacting the heated first surface of the firstsubstrate with a first surface of a epoxy adhesive to tack the epoxyadhesive to the first surface of the first substrate, moving a rolleracross either a release liner on a second surface of the epoxy adhesiveor a second surface of the first substrate to remove air bubbles at aninterface between the first surface of the epoxy adhesive and the firstsurface of the first substrate, and cooling the first substrate and theepoxy adhesive to a temperature of 22° C. or less. Subsequently, themethod can further include heating a first surface of a second substrateto a temperature of between 40° C. and 120° C. and, with the epoxyadhesive tacked to the first surface of the first substrate, contactingthe heated first surface of the second substrate with a second surfaceof the epoxy adhesive to tack the epoxy adhesive to the first surface ofthe second substrate. The method can further include moving a rolleracross a second surface of the second substrate to remove air bubbles atan interface between the second surface of the epoxy adhesive and thefirst surface of the second substrate then, after tacking the epoxyadhesive to the first substrate and the second substrate, partiallycuring the epoxy adhesive by heating the first substrate, the secondsubstrate, and the epoxy adhesive to a temperature of between about 80°C. and about 140° C. for a duration of between about 10 minutes andabout 20 minutes. After partially curing the epoxy adhesive, the epoxyadhesive is fully cured by heating the first substrate, the secondsubstrate, and the epoxy adhesive within a press to a temperature ofbetween 100° C. and 300° C. for a duration of between 20 minutes and 200minutes and at a pressure of between 40 psi and 100 psi.

In another embodiment, an ink jet printhead can include a firstsubstrate, a second substrate, an epoxy adhesive interposed between thefirst substrate and the second substrate that physically connects thefirst substrate to the second substrate. The epoxy adhesive can includea cresol novolac and bisphenol A epoxy resin and can have a lap shearstrength greater than 200 psi bonding the first substrate to the secondsubstrate. The ink jet printhead can further include an ink within theink jet printhead that physically contacts the epoxy adhesive, whereinthe ink is an ultraviolet gel ink or a pigmented ink, and the epoxyadhesive has a mass uptake of less than 0.4% when exposed continuouslyto the ink for 20 weeks.

BRIEF DESCRIPTION OF THE DRAWINGS

The accompanying drawings, which are incorporated in and constitute apart of this specification, illustrate embodiments of the presentteachings and together with the description, serve to explain theprinciples of the disclosure. In the figures:

FIG. 1 is a cross section of an exemplary ink jet printhead portionformed in accordance with an embodiment of the present teachings; and

FIG. 2 a perspective view of a printer including one or more printheadsin accordance with an embodiment of the present teachings.

It should be noted that some details of the FIGS. have been simplifiedand are drawn to facilitate understanding of the present teachingsrather than to maintain strict structural accuracy, detail, and scale.

DETAILED DESCRIPTION

Reference will now be made in detail to exemplary embodiments of thepresent teachings, examples of which are illustrated in the accompanyingdrawings. Wherever possible, the same reference numbers will be usedthroughout the drawings to refer to the same or like parts.

As used herein, unless otherwise specified, the word “printer”encompasses any apparatus that performs a print outputting function forany purpose, such as a digital copier, bookmaking machine, facsimilemachine, a multi-function machine, electrostatographic device, etc.Unless otherwise specified, the word “polymer” encompasses any one of abroad range of carbon-based compounds formed from long-chain moleculesincluding thermoset polyimides, thermoplastics, resins, polycarbonates,epoxies, and related compounds known to the art.

Achieving reliable adhesion between many different ink jet printheadlayers and materials, particularly at the harsh environmental conditionsfound in current ink jet printhead uses, is a concern for devicemanufacturers. An embodiment of the present teachings can result in amore robust physical adhesive connection between the various laminatedlayers within a printhead, particularly with regard to resistance tochemically harsh inks such as acrylate-based ultraviolet (UV) inks andpigmented inks, and may result in decreased stresses on theinterconnection which electrically couples a piezoelectric transducer(PZT) to a circuit layer such as a printed circuit board or flexibleprinted circuit.

Printhead structures are known in the art and include many layerslaminated together. The adhesives used for lamination must resistreaction with chemically harsh inks, bond well to surfaces of differentmaterials to prevent rupture during high-pressure printing, and hold upduring high temperature printing, for example during printing with solidinks. FIG. 1 depicts a portion of an exemplary ink jet printheadstructure 10 that may be formed using an embodiment of the presentteachings. The FIG. 1 printhead structure 10 includes a compliant wall12, an external manifold 14, and a diverter 16 attached to the externalmanifold 14 with an external manifold adhesive 18. FIG. 1 furtherdepicts a boss plate 20 attached to the diverter 16 with a diverterattach adhesive 22. In an embodiment, the compliant wall 12 can includethermoplastic polyimide, the external manifold 14 can include aluminum,and the boss plate 20 can include stainless steel. The external manifold14 can receive liquid ink (not individually depicted for simplicity)during use which has been melted from solid ink blocks, a gel ink, a UVink, or another liquid ink in preparation for printing, and maintain theink at a print temperature. FIG. 1 further depicts a body 32, a verticalinlet 34, a separator 36, a particulate filter (rock screen) layer 38including a rock screen 40, a front end manifold 42, and an apertureplate 44 having a nozzle 46. The aperture plate 44 can be attached tothe front end manifold 42 with an aperture plate adhesive 48. In anembodiment, the body 32, the separator 36, and the front end manifold 42can include a metal such as stainless steel, and the vertical inlet 34,the rock screen layer 38, the aperture plate adhesive 48, and theaperture plate 44 can each include one or more polymers. The assembly 10can be manufactured according to known processing techniques, such as aprocess including the use of a stack press under high pressure. FIG. 1further depicts a substrate 52 such as a semiconductor wafer section,glass layer, metal layer, etc., a standoff layer 54, a printheaddiaphragm (membrane) 56, a boss plate adhesive 70, a diaphragm adhesive72, an application specific integrated circuit (ASIC) 58 attached to thesemiconductor wafer section, and an interconnect layer 60 such as aflexible (flex) circuit or printed circuit board electrically coupled tothe ASIC 58. As discussed above, the substrate 52 can be a silicon,gallium arsenide, metal, glass, etc. Further, the standoff layer 54 canbe silicon dioxide and/or SU-8 photoresist. The diaphragm 56 can be ametal such as titanium, nickel, or a metal alloy. The substrate 52 mayinclude a circuit pattern. It will be appreciated that the depiction ofthe FIG. 1 is a small portion of a printhead depicting a single ink port74 and nozzle 46, and that other structures may be added or existingstructures may be removed or modified. A printhead with current designsmay have four ink inlets, one for each color (cyan, magenta, yellow, andblack in a CMYK color model, for example), and 7040 nozzles. Thestructure of FIG. 1 may be formed using an embodiment of the presentteachings and may include a structure in accordance with an embodimentthe present teachings.

A desirable adhesive for printhead applications would be able to bondany combination of metal layers (e.g., stainless steel, aluminum, etc.)and/or polyimide layers. In selecting an adhesive, similar formulationsmay have differing properties and operating characteristics. Extensivein-house testing is required to characterize the properties of anadhesive to determine whether it has the necessary characteristics for aspecific use. While a supplier may publish some operatingcharacteristics, other unknown characteristics may be of particularinterest to a manufacturer searching for a suitable adhesive and thuscharacterization of the adhesive by the manufacturer is necessary. Alarge number of adhesive formulations are commercially available andidentifying an adhesive that has the necessary characteristics oftenpresents a formidable challenge. Further complicating the selection isthe fact that an adhesive may embody different characteristics atdifferent thicknesses, different application processes, and at differenttemperatures. Additionally, an adhesive may react differently whenexposed to different chemicals having similar formulations, for exampleto similar but different ink formulations. The variety of combinationsof epoxy resins and curing agents provides wide latitude in chemical andmechanical properties at the final cured stage.

An embodiment of the present teachings can include the use of anadhesive for physically attaching together two or more printhead parts.In use, the adhesive may be subjected to harsh chemical inks, such aspigmented inks and UV gel inks and to high temperatures and pressuresassociated with printing, for example, solid inks. In an embodiment, theadhesive may be an epoxy-based liquid adhesive that is a thermal settingpolymer, and may be a TechFilm TF0063-86 (i.e., TF0063-86) availablefrom Resin Designs, LLC of Woburn, Mass. In an embodiment, the adhesive,when properly processed in accordance with an embodiment of the presentteachings, may enable the fabrication of a high performance, low cost,high density ink jet printhead. The adhesive is chemically resistant tohostile inks used in current printing applications and maintainsadhesion in high-temperature, high-pressure printing conditions.

The adhesive identified above, TF0063-86, is a B-stage, two part epoxy.As with many epoxies, TF0063-86 includes an epoxy resin and an epoxycuring agent (i.e., hardener) which are mixed together to provide thefinal adhesive. More specifically, the TF0063-86 epoxy film adhesive isa blend of base components including two bisphenol A epoxy resins,cresol novolac resin, an imidazole amine hardener, and a latent curingagent, dicyandiamide (i.e., “DICY”). The blend of the BisPhenol A EpoxyResins (DGEBA resins) and the Cresol Novolac Resin coupled with thehardener and latent curing agent give adequate thermo-oxidationresistance, good workability, long pot life, and higher heat resistancethan some other adhesives. Additionally, the relatively small amount ofthe DICY latent curing agent present, e.g., about 2% to 3% by weight,reduces the number of amine linkages in the cured material which areotherwise susceptible to oxidative attack. The combination of resins andcuring agent chemistries and ratios provide an extended pot life at roomtemperature. Solvents, for example 2-butoxy ethyl acetate, may be usedto dilute the uncured epoxy blend such that the material may be coatedonto a liner for use as a film. In addition, a minimum amount of thissolvent may be left remain for improved ease of handling of the adhesivefilms. Laser ablation work has shown that this film may be accuratelycut into specific geometries.

A chemical structure of the cresol novolac resin may be:

Another chemical structure of the cresol novolac resin may be:

The curing agent used may be DICY, which has the form:

DICY is a representative latent during agent that forms crystals whenprocessed in accordance with the present teachings. It may be used inthe form of a fine powder dispersed within the resin. The material has avery long pot life, for example 6 to 12 months. DICY cures at a hightemperature, for example from about 160° C. to about 180° C. in about 20minutes to about 60 minutes. Cured DICY resins have a good adhesivenessand are less prone to staining that some other resins. DICY may be usedin one-part adhesives, powder paints, and pre-impregnated compositefibers (i.e., “pre-pregs”).

Another co-curing agent that may be used in the epoxy adhesive isimidazole. Imidazoles are characterized by a relatively long pot life,the ability to form cured resin with a high heat deformation temperatureby thermally treating at a medium temperature (80° C. to 120° C.) for arelatively short duration, and the availability of various derivativeshaving moderate reactivity that improves workability. When used as aco-curing agent with DICY, imidazole may exhibit a better pot life, afaster curing speed, and a higher heat resistance of the cured substancethan when an adhesive is used with some other co-curing agents.

Some representative chemical structures of various imidazoles, one ormore of which may be included as a co-curing agent, include1-methylimidazole:

2-ethyl, 4-methyl imidazole:

and 1-cyanoethyl-2-undecylimidazolium trimellitate:

The TF0063-86 may be supplied as a solid adhesive interposed between afirst release liner and a second release liner, where the adhesive isused to attach a first substrate to a second substrate. In an embodimentof the present teachings, the release liner is removed to expose a firstadhesive surface, the first adhesive surface is contacted to a surfaceof the first substrate, the second release liner is removed to expose asecond adhesive surface, and the second adhesive surface is contacted toa surface of the second substrate. The embodiments described below arewith reference to a solid adhesive interposed between a first releaseliner and a second release liner, although other embodiments arecontemplated.

In an embodiment of the present teachings, the adhesive may be used toadhere or bond two surfaces together using a particular process to applythe adhesive. The process may result in the adhesive having variousdesirable operating characteristics or properties for a printheadfabrication application that are not found if a different applicationprocess is used. A novel fabrication process has been developed toenable the use of TF0063-86 epoxy adhesive for printhead interstitialbonding with little or no squeeze out at high pressure and good bondingstrength with little or no formation of trapped air bubbles.

The procedure for attaching two or more surfaces together using theTF0063-86 adhesive may include an embodiment of the following process.While the process is described with reference to the attachment of apolyimide film as a first substrate and a stainless steel sheet as asecond substrate using the TF0063-86 film for simplicity of description,it will be understood that the TF0063-86 epoxy adhesive may be used toattach other substrates together, for example various metals, polyimidelayers, polymers other than polyimide, and combinations thereof.

In an embodiment, the substrate surfaces that are to be bonded areprepared using a surface preparation process. The composition of thesubstrate material will depend on the application and may include metalssuch as stainless steel or aluminum, or polymers such as polyimide otherothers. The surface preparation can include cleaning the first andsecond substrates using a solvent such as isopropyl alcohol(isopropanol, IPA) to remove trace contaminating substances such as oilsand airborne particulates.

After cleaning the bonding surfaces with a solvent, the surfacepreparation may also include subjecting the bonding surfaces to a plasmacleaning process. In an embodiment, the plasma cleaning process mayinclude an oxygen plasma cleaning process for a duration of from about 2minutes to about 10 minutes. The plasma cleaning process is used tofurther remove any contaminants from the bonding surfaces and also toroughen the substrate to increase the bonding surface area for improvedadhesion.

After surface preparation, the adhesive and first substrate are preparedfor tacking with the adhesive. In an embodiment, the first release lineris removed from the first surface of the solid adhesive. At least thebonding surface of the first substrate is heated to a tackingtemperature of between about 40° C. and about 120° C., or between about50° C. and about 100° C., or between about 50° C. and about 60° C. Thisheating may be performed, for example, by heating the first substrate ona hot plate or within an oven. The entire first substrate may be heated,or only the bonding surface may be heated. After heating the bondingsurface of the first substrate, the first surface of the solid adhesiveis contacted with the bonding surface of the first substrate, forexample by placing the first surface of the adhesive onto the bondingsurface to tack the first substrate to the adhesive.

At the tacking temperature, the first substrate-adhesive assembly isrolled by moving a roller under pressure across either the exposedsecond release liner on the second surface of the adhesive, across asecond surface (back side) of the first substrate, or both. This rollingstage assists in removing air bubbles at the interface between the firstsurface of the adhesive and the bonding surface of the first substrate.In an embodiment, the roller may be rolled across the firstsubstrate-adhesive assembly at a pressure, for example at a rollerpressure of between about 1 psi and about 10 psi, or between about 1 psiand about 5 psi, against the surface.

After this processing stage, the first substrate-adhesive assembly iscooled to ambient temperature of 22° C. or less to result in the firstsubstrate being tacked to the adhesive. This tack procedure serves towet the adhesive onto the substrate to reduce or eliminate air bubbles.

Subsequently, the second release liner is removed from the secondsurface of the solid adhesive. At least the bonding surface of thesecond substrate is heated to the tacking temperature as described abovefor the first substrate, between about 40° C. and about 120° C., orbetween about 50° C. and about 100° C., or between about 50° C. andabout 60° C. for a duration of between about 1 minute and about 5minutes. This heating may be performed, for example, by heating thesecond substrate on a hot plate or within an oven. The entire secondsubstrate may be heated, or only the bonding surface may be heated.After heating the bonding surface of the second substrate, the secondsurface of the solid adhesive is contacted with the bonding surface ofthe second substrate, for example by placing the second surface of theadhesive onto the bonding surface to tack the second substrate to theadhesive.

At the tacking temperature, the second substrate-adhesive assembly isrolled by moving a roller under pressure across the back of the secondsubstrate to assist in the removal of bubbles at the interface betweenthe second surface of the adhesive and the bonding surface of the secondsubstrate. In an embodiment, the roller may be rolled across the secondsubstrate-adhesive assembly at a pressure, for example at a rollerpressure of between about 1 psi and about 10 psi, or between about 1 psiand about 5 psi, against the surface. After rolling the secondsubstrate-adhesive assembly, first and second substrates are partiallyadhered together using the tacky TF0063-86 adhesive. The three layerassembly, including the first and second substrates and the TF0063-86adhesive, may be cooled to ambient temperature, or may proceed directlyto the next processing stage without cooling, for example by ramping thetemperature to the partial curing temperature as described below. Whilethe process is described with reference to a three layer assembly, thethree layer assembly may include additional substrates attached to thethree layer assembly, for example using other TF0063-86 adhesive layersor other portions of the existing TF0063-86 adhesive.

After rolling the second substrate-adhesive assembly to form the threelayer assembly, an adhesive partial curing process is performed. Thethree layer assembly may be heated to a partial curing temperature ofbetween about 80° C. and about 140° C., or between about 90° C. andabout 120° C., or between about 100° C. and about 120° C., for exampleabout 120° C. The three layer assembly may be heated, for example, on ahot plate or in an oven. Once the three layer assembly reaches thepartial curing temperature, heat is applied to the three layer assemblyfor a duration of between about 10 minutes and about 20 minutes, forexample about 15 minutes. This partial curing process is a crucial stageto decrease, minimize, or eliminate squeeze out of the adhesive duringsubsequent processing. If a temperature and/or duration of this partialcuring stage is insufficient or excessive, adhesive squeeze out,over-curing of the adhesive, or damage to the adhesive components mayoccur.

After the partial curing process, the three layer assembly is heatedunder pressure, for example in a jet stack press, to a final bondingtemperature to complete the bonding process to form a fully curedadhesive. In an embodiment, the assembly is heated to a final bondingtemperature of between about 100° C. and about 300° C., or between about150° C. and about 200° C., or between about 180° C. and about 200° C.,for example about 190° C. Once the three layer assembly reaches thefinal bonding temperature, heat is applied to the three layer assemblyfor a duration of between about 20 minutes and about 200 minutes, orbetween about 60 minutes and about 100 minutes, for example about 70minutes. During the application of the final bonding temperature, abonding pressure of between about 40 psi and about 100 psi, or at apressure of 70 psi or less, or at a maximum pressure of 70 psi, forexample a pressure of about 55 psi, is applied to the three layerassembly within the jet stack press. After curing the adhesive at thefinal bonding temperature under the bonding pressure for theabove-stated duration, the pressure and temperature are decreased toambient levels to complete the bonding process. For purposes of thisdisclosure, a “fully cured” adhesive refers to an adhesive that issufficiently cured for use of the printhead (e.g., more than 95% cured).A curing agent such as DICY and/or a co-curing agent such as imidazolemay or may not remain in the fully cured adhesive depending, forexample, on whether the fully cured adhesive is 100% cured. In anembodiment, depending on a ratio of epoxy to curing agent in thepre-cured formulation, the curing agent such as DICY may remain in thematrix after curing even if the adhesive is 100% cured.

In an embodiment, TF0063-86 epoxy adhesive may be used, referring toFIG. 1, as the external manifold adhesive 18, the diverter attachadhesive 22, the aperture plate adhesive 48, the boss plate adhesive 70,the diaphragm adhesive 72, or generally any printhead adhesive. Theepoxy adhesive may be used to physically attach any combination of oneor more metals (e.g., stainless steel, aluminum, copper, metal alloy,etc.), one or more semiconductors (e.g., silicon, gallium arsenide,etc.), and/or one or more organic or inorganic polymers (e.g.,polyimide, nylon, silicone, etc.).

During testing, it was found that a cured epoxy adhesive preparedaccording one or more of the process embodiments described abovedemonstrated characteristics and properties well suited for printheadapplications. In one test, nozzles were drilled into an adhesive sampleincluding the TF0063-86 adhesive prepared according to an embodimentdescribed above and evaluated for bubbles. No bubbles greater than 20 μmwere detected using this process.

Wicking or squeeze out of adhesive occurs when the cured adhesive has achange in dimension of 5% or greater, which can lead to leakage of inkor bursting of the printhead during high-pressure printing. For example,pressures within a solid ink jet printhead can reach up to 10 psi. Thesubject material demonstrated a squeeze out of less than 5%. A squeezeout test was performed on an assembly including TF0063-86 adhesiveinterposed between a stainless steel layer and a polyimide layer with500 μm nozzles processed according to an embodiment described above. Thecompleted adhesive had a thickness of about 1 mil. All of the nozzleswere open subsequent to final bonding in a jet stack press. A differentprinthead adhesive prepared using the same process failed to performsatisfactorily with complete blockage of the nozzles. Additionally, thesame adhesive without the partial curing stage failed.

To provide sufficient bonding of metal to metal, metal to polyimide, orpolyimide to polyimide, an adhesive must provide a lap shear strength,regardless of the material, of greater than about 200 psi. Someadhesives minimally meet this tolerance, do not meet this tolerance, ormeet the tolerance only at room temperatures. In a lap shear samplepreparation, the stainless steel adherends were cleaned for five minutesin an ultrasonic bath of IPA, then another four minutes of detergentultrasonic cleaning, followed by a five minutes of a rinse in deionizedwater, followed by oven drying at 100° C. for 30 minutes, then a plasmaclean. The TF0063-86 adhesive was bonded between the adherends asdescribed above at a thickness of 1.0 mil. For an area of 0.62 in², amaximum load was found to be 1627.2 pound-force (lbf), and the lap shearstrength was found to be greater than 2600 psi (2625 psi) bonding afirst substrate to a second substrate. The material prepared accordingto the method described above thus demonstrated good bonding strengthfor printhead applications.

Additionally, weight gain (i.e., mass uptake) of an adhesive duringexposure to harsh inks results in swelling, which can cause leakage orbursting of the printhead during high-temperature, high-pressure use. Inan embodiment of the present teachings, when exposed to gel UV ink, thecured epoxy adhesive resisted weight gain and swelling (i.e., less than0.4% weight gain) when exposed to harsh inks at 90° C. continuously for20 weeks and is thus compatible with harsh inks. In contrast, someconventional inks used in printhead fabrication show marked weightchange when exposed to harsh inks, in some cases a percent change inweight of as much as 160% after less than 1000 hours of testing.

While some epoxy adhesives are cured using high pressures, for examplepressures greater than 200 psi, the subject material may be cured atpressures of 200 psi or less, for example about 55 psi. Extremepressures are avoided where possible during printhead manufacture, asvarious printhead structures such as piezoelectric elements andelectrical circuits may be damaged during high pressure assemblyprocesses. Still, high pressures are used in conventional processes withsome conventional adhesives to improve adhesive bonding and printheadreliability.

After forming a laminated printhead structure such as the structure ofFIG. 1 using a TF0063-86 adhesive, the printhead is filled with an ink206 (FIG. 2), for example a UV ink or a pigmented ink. These inks areparticularly chemically reactive with conventional epoxy adhesivesapplied using conventional techniques, which are exposed to the inkwithin the printhead. In an embodiment, the subject materials resistschemical reaction with the ink, for example weight gain and swelling(mass uptake).

Additionally, in an embodiment, a storage modulus of the epoxy adhesiveis between about 100 megapascals (MPa) and about 1500 MPa at atemperature of 20° C. and between about 3 MPa and about 700 MPa at atemperature of 120° C. An embodiment of the adhesive may further have ashelf life of greater than one month at 20° C. and greater than one yearat 0° C.

To reduce ink leakage between adjacent layers, a particle size of afiller material within an adhesive should be as small as possible.Fillers within the subject material may include a plurality ofparticles, wherein a maximum diameter (or a maximum dimension in anydirection) of each of the plurality of particles is 1.0 μm or less.Filler materials may include one or more of calcium carbonate, silica,alumina, alumina trihydrate, barium sulfate, titania, and kaolin clay.

FIG. 2 depicts a printer 200 including a printer housing 202 into whichat least one printhead 204 including an embodiment of the presentteachings has been installed and that encases the printhead 204. Duringoperation, ink 206 is ejected from one or more printheads 204. Theprinthead 204 is operated in accordance with digital instructions tocreate a desired image on a print medium 208 such as a paper sheet,plastic, etc. The printhead 204 may move back and forth relative to theprint medium 208 in a scanning motion to generate the printed imageswath by swath. Alternately, the printhead 204 may be held fixed and theprint medium 208 moved relative to it, creating an image as wide as theprinthead 204 in a single pass. The printhead 204 can be narrower than,or as wide as, the print medium 208. In another embodiment, theprinthead 204 can print to an intermediate surface such as a rotatingdrum or belt (not depicted for simplicity) for subsequent transfer to aprint medium.

Notwithstanding that the numerical ranges and parameters setting forththe broad scope of the present teachings are approximations, thenumerical values set forth in the specific examples are reported asprecisely as possible. Any numerical value, however, inherently containscertain errors necessarily resulting from the standard deviation foundin their respective testing measurements. Moreover, all ranges disclosedherein are to be understood to encompass any and all sub-ranges subsumedtherein. For example, a range of “less than 10” can include any and allsub-ranges between (and including) the minimum value of zero and themaximum value of 10, that is, any and all sub-ranges having a minimumvalue of equal to or greater than zero and a maximum value of equal toor less than 10, e.g., 1 to 5. In certain cases, the numerical values asstated for the parameter can take on negative values. In this case, theexample value of range stated as “less than 10” can assume negativevalues, e.g. −1, −2, −3, −10, −20, −30, etc.

While the present teachings have been illustrated with respect to one ormore implementations, alterations and/or modifications can be made tothe illustrated examples without departing from the spirit and scope ofthe appended claims. For example, it will be appreciated that while theprocess is described as a series of acts or events, the presentteachings are not limited by the ordering of such acts or events. Someacts may occur in different orders and/or concurrently with other actsor events apart from those described herein. Also, not all processstages may be required to implement a methodology in accordance with oneor more aspects or embodiments of the present teachings. It will beappreciated that structural components and/or processing stages can beadded or existing structural components and/or processing stages can beremoved or modified. Further, one or more of the acts depicted hereinmay be carried out in one or more separate acts and/or phases.Furthermore, to the extent that the terms “including,” “includes,”“having,” “has,” “with,” or variants thereof are used in either thedetailed description and the claims, such terms are intended to beinclusive in a manner similar to the term “comprising.” The term “atleast one of” is used to mean one or more of the listed items can beselected. Further, in the discussion and claims herein, the term “on”used with respect to two materials, one “on” the other, means at leastsome contact between the materials, while “over” means the materials arein proximity, but possibly with one or more additional interveningmaterials such that contact is possible but not required. Neither “on”nor “over” implies any directionality as used herein. The term“conformal” describes a coating material in which angles of theunderlying material are preserved by the conformal material. The term“about” indicates that the value listed may be somewhat altered, as longas the alteration does not result in nonconformance of the process orstructure to the illustrated embodiment. Finally, “exemplary” indicatesthe description is used as an example, rather than implying that it isan ideal. Other embodiments of the present teachings will be apparent tothose skilled in the art from consideration of the specification andpractice of the disclosure herein. It is intended that the specificationand examples be considered as exemplary only, with a true scope andspirit of the present teachings being indicated by the following claims.

Terms of relative position as used in this application are defined basedon a plane parallel to the conventional plane or working surface of aworkpiece, regardless of the orientation of the workpiece. The term“horizontal” or “lateral” as used in this application is defined as aplane parallel to the conventional plane or working surface of aworkpiece, regardless of the orientation of the workpiece. The term“vertical” refers to a direction perpendicular to the horizontal. Termssuch as “on,” “side” (as in “sidewall”), “higher,” “lower,” “over,”“top,” and “under” are defined with respect to the conventional plane orworking surface being on the top surface of the workpiece, regardless ofthe orientation of the workpiece.

1. A method for forming an ink jet printhead, comprising: heating afirst surface of a first substrate to a temperature of between 40° C.and 120° C.; contacting the heated first surface of the first substratewith a first surface of a epoxy adhesive to tack the epoxy adhesive tothe first surface of the first substrate; moving a roller across eithera release liner on a second surface of the epoxy adhesive or a secondsurface of the first substrate to remove air bubbles at an interfacebetween the first surface of the epoxy adhesive and the first surface ofthe first substrate; cooling the first substrate and the epoxy adhesiveto a temperature of 22° C. or less; then heating a first surface of asecond substrate to a temperature of between 40° C. and 120° C.; withthe epoxy adhesive tacked to the first surface of the first substrate,contacting the heated first surface of the second substrate with asecond surface of the epoxy adhesive to tack the epoxy adhesive to thefirst surface of the second substrate; moving a roller across a secondsurface of the second substrate to remove air bubbles at an interfacebetween the second surface of the epoxy adhesive and the first surfaceof the second substrate; then after tacking the epoxy adhesive to thefirst substrate and the second substrate, partially curing the epoxyadhesive by heating the first substrate, the second substrate, and theepoxy adhesive to a temperature of between about 80° C. and about 140°C. for a duration of between about 10 minutes and about 20 minutes; andafter partially curing the epoxy adhesive, fully curing the epoxyadhesive by heating the first substrate, the second substrate, and theepoxy adhesive within a press to a temperature of between 100° C. and300° C. for a duration of between 20 minutes and 200 minutes and at apressure of between 40 psi and 100 psi.
 2. The method of claim 1,further comprising: the heating of the first substrate heats the firstsubstrate to a temperature of between 50° C. and 60° C.; the heating ofthe second substrate heats the second substrate to a temperature ofbetween 50° C. and 60° C.; the partially curing of the epoxy adhesiveheats the epoxy adhesive to a temperature of about 120° C.; and thefully curing of the epoxy adhesive heats the epoxy adhesive to atemperature of about 190° C. at a pressure of about 55 psi.
 3. Themethod of claim 1, further comprising: the moving of the roller acrosseither the release liner on the second surface of the epoxy adhesive ora second surface of the first substrate is performed at a rollerpressure of between 1 psi and 10 psi; and the moving of the rolleracross the second surface of the second substrate is performed at aroller pressure of between 1 psi and 10 psi.
 4. The method of claim 1,further comprising: cleaning the first surface of the first substrateand the first surface of the second substrate in a solvent; and aftercleaning the first surface of the first substrate and the first surfaceof the second substrate in the solvent, exposing the first surface ofthe first substrate and the first surface of the second substrate to aplasma to further clean the first surface of the first substrate and thefirst surface of the second substrate.
 5. The method of claim 1, whereinthe first substrate is one of a polymer and a metal, and the secondsubstrate is the other of a polymer and a metal.
 6. The method of claim1, further comprising: filling the ink jet printhead with an ink,wherein the ink comprises at least one of an ultraviolet (UV) gel inkand a pigmented ink; and exposing the fully cured epoxy adhesive to theink.
 7. An ink jet printhead, comprising: a first substrate; a secondsubstrate; an epoxy adhesive interposed between the first substrate andthe second substrate that physically connects the first substrate to thesecond substrate, wherein the epoxy adhesive: comprises a cresol novolacand bisphenol A epoxy resin; has a lap shear strength greater than 200psi bonding the first substrate to the second substrate; and an inkwithin the ink jet printhead that physically contacts the epoxyadhesive, wherein the ink is an ultraviolet gel ink or a pigmented ink,and the epoxy adhesive has a mass uptake of less than 0.4% when exposedcontinuously to the ink for 20 weeks.
 8. The ink jet printhead of claim7, wherein a chemical structure of the cresol novolac resin comprises:


9. The ink jet printhead of claim 7, wherein the epoxy adhesive furthercomprises a dicyandiamide curing agent and a chemical structure of thedicyandiamide curing agent comprises:


10. The ink jet printhead of claim 7, wherein the epoxy adhesive furthercomprises an imidazole co-curing agent and a chemical structure of theimidazole co-curing agent is:


11. The ink jet printhead of claim 7, wherein the epoxy adhesive has alap shear strength greater than 2600 psi bonding the first substrate tothe second substrate.
 12. The ink jet printhead of claim 7, wherein astorage modulus of the epoxy adhesive is between about 100 megapascals(MPa) and about 1500 MPa at a temperature of 20° C. and between about 3MPa and about 700 MPa at a temperature of 120° C.
 13. The ink jetprinthead of claim 7, wherein the epoxy adhesive further comprises afiller material comprising a plurality of particles, wherein a maximumdimension of each of the plurality of particles is 1.0 μm or less. 14.The ink jet printhead of claim 13, wherein the filler material comprisesone or more of calcium carbonate, silica, alumina, alumina trihydrate,barium sulfate, titania, and kaolin clay.
 15. The ink jet printhead ofclaim 7, wherein the epoxy adhesive has a shelf life of greater than onemonth at 20° C. and greater than one year at 0° C.